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420 stainless steel is a hardenable martensitic stainless steel that contains a minimum of 12% chromium, which provides good corrosion resistance properties, Its best corrosion resistance is achieved when the metal is hardened and surface ground or polished. 420 grade has a higher carbon content than is designed to enhance strength and hardness characteristics, however, the corrosion resistance of 420 stainless steel is not as good as the common austenitic grades.
420 stainless steel has good ductility in the annealed condition but can be hardened to a minimum Rockwell hardness of 50 HRC, which is the highest hardness of the 12% chromium grades, the typical application is for knives. 420 stainless steel is magnetic due to its microstructure of martensitic.
The hardness of 420 stainless steel: Rockwell HRB 96 max.
420 stainless steel heat treatment: Heat to 1500-1650°F (816-899°C), cool slowly
420 stainless steel melting point: 2649 – 2750°F (1454 – 1510°C)
The chemical composition of 420 stainless steel contains 12–14% chromium (Cr) and iron, high carbon content (min 0.15%), and less nickel content (0.75% Max).
ASTM | AISI (UNS) | C, | Si, Max | Mn, Max | P, Max | S, Max | Cr | Ni, Max | Mo, Max | Iron |
---|---|---|---|---|---|---|---|---|---|---|
ASTM A240 420 | SS 420 (UNS S42000) | 0.15, Min | 1.00 | 1.00 | 0.040 | 0.030 | 12.0-14.0 | 0.75 | 0.50 | Bal. |
ASTM A276 420 | SS 420 (UNS S42000) | 0.15, Min | 1.00 | 1.00 | 0.040 | 0.030 | 12.0-14.0 | – | – | Bal. |
EN10088-2 1.4028 | 0.26-0.35 | 1.00 | 1.50 | 0.040 | 0.015 | 12.0-14.0 | – | – | Bal. | |
EN10088-2 1.4021 | 0.16-0.25 | 1.00 | 1.50 | 0.040 | 0.015 | 12.0-14.0 | – | Bal |
Empering Temperature (°C) | Tensile Strength (MPa) | Yield Strength 0.2% Proof (MPa) | Elongation (% In 50mm) | Hardness Brinell (HB) |
---|---|---|---|---|
Annealed * | 655 | 345 | 25 | 241 Max |
399°F (204°C) | 1600 | 1360 | 12 | 444 |
600°F (316°C) | 1580 | 1365 | 14 | 444 |
800°F (427°C) | 1620 | 1420 | 10 | 461 |
1000°F (538°C) | 1305 | 1095 | 15 | 375 |
1099°F (593°C) | 1035 | 810 | 18 | 302 |
1202°F (650°C) | 895 | 680 | 20 | 262 |
* Annealed Tensile Properties Are Typical For Condition A Of ASTM A276; Annealed Hardness Is The Specified Maximum. |
The table below provides the physical properties of grade 420 in their annealed state:
Grade | Density (Kg/M3) | Elastic Modulus (GPa) | Mean Coefficient Of Thermal Expansion (Μm/M/°C) | Thermal Conductivity (W/M.K) | Specific Heat 0-100°C (J/Kg.K) | Electrical Resistivity (NΩ.M) | |||
---|---|---|---|---|---|---|---|---|---|
0-100°C | 0-315°C | 0-538°C | At 100°C | At 500°C | |||||
420 | 7800 | 200 | 10.3 | 10.8 | 11.7 | 24.9 | – | 460 | 550 |
EU EN | USA – | Germany DIN,WNr | Japan JIS | France AFNOR | England BS | China GB | Sweden SS | Poland PN | Czechia CSN | Russia GOST |
---|---|---|---|---|---|---|---|---|---|---|
EU EN | USA – | Germany DIN,WNr | Japan JIS | France AFNOR | England BS | China GB | Sweden SS | Poland PN | Czechia CSN | Russia GOST |
X20Cr13 (1.4021) | 420/S42010 | X20Cr13 | SUS420J1 | X20Cr13Z20C13 | 420S29420S37 | 2Cr13X20Cr13 | 2303 | 2H13 | 17022 | 20KH13 |
Grade 420 stainless steel is a high-carbon steel with a minimum chromium content of 12%. Like other martensitic stainless steels, grade 420 can also be hardened through heat treatment. Martensitic stainless steels are ones with high hardness and high carbon content. These steels are generally fabricated using methods that require hardening and tempering treatments. The operating conditions of martensitic steels are affected by loss of material strength at high temperatures and a decrease in ductility at negative temperatures. AISI 420 steel provides both outstanding corrosion resistance and exceptional wear resistance.
Under hardened conditions, grade 420 steels are resistant to fresh water, alkalis, air, foods and mild acids. The steel grades with a smooth surface finish have excellent performance. The corrosion resistance properties of grade 420 will tend to fall under annealed conditions. The corrosion resistance of grade 420 is lower than that of grade 430 Ferritic alloys with 17% chromium, grade 410 steel and other austenitic grades. Grade 420 steels have good corrosion resistance against food, but continuous exposure of metals to unwashed food substances can lead to pitting corrosion.
Its heat resistance depends on the content of its alloying elements and heat treatment process.
Typically, SS 420 has limited heat resistance and is better suited for low-temperature operating environments. Its maximum service temperature is usually 650℃. Beyond this temperature range, the stainless steel will begin to occur nitride precipitation, resulting in excessive grain growth and grain boundary corrosion, which can lead to a serious increase in the thermal embrittlement of the material.
If the heat resistance of 420 grade needs to be improved, heat treatment processes, such as solution treatment and quenching and annealing, can be performed. These treatments can improve the grain boundary structure and grain size of the material, thus improving its heat resistance.
Overall, the heat resistance of 420 SSl is low compared to other heat-resistant stainless steel and is suitable for use in low-temperature environments. For high-temperature applications, it is recommended to choose a stainless steel material with better heat resistance.
420 stainless steel is a high carbon content stainless steel with excellent corrosion resistance and mechanical properties. It can be further improved by heat treatment. Using the annealing process, grade 420 stainless steel is heated to 840 to 900°C, then slowly furnace cooled at 600°C and finally air cooled. For process annealing, Grade 420 steel is heated to 735 to 785°C and then air-cooled. For hardening, 420 grade steel is heated to 980 to 1035°C and then air or oil quenched. Temper at 150 to 370°C to obtain high hardness and good mechanical properties, but avoid tempering treatments between 425 and 600°C.
Grade 420 stainless steels are welded using welding rods, coated with grade 420 metals, to achieve high-strength joints. During the process, steels are pre-heated at 150 to 320°C and post-heated at 610 to 760°C. In the “as welded” condition, parts are welded using grade 309 filler rods to achieve ductile joints. However, grade 309 electrodes or rods are recommended for welding grade 420 steels by AS 1554.6.
Grade 420 steels can be easily machined in their annealed state, but they are difficult to machine having a hardness greater than 30HRC. One of the most readily available machined alternatives is the free-machining grade 416 steels.
The following are common processing methods for 420 stainless steel:
420 stainless steel has high hardness and wear resistance, as well as good corrosion resistance, and can be used to manufacture knives, blades, surgical instruments, bearing components, assembly parts, and so on. The material is also easy to process and malleable, easy to be processed into various shapes and sizes through cutting, forging, heat treatment and other processes. It is not usually used at temperatures exceeding 800oF (427oC) due to quick hardening and loss of corrosion resistance.
420 is a martensitic stainless steel grade. As such, its major alloying elements are chromium and carbon, with small amounts of manganese, silicon, and sometimes molybdenum and nickel. 304 is an austenitic stainless steel alloy that contains a substantial amount of nickel along with more chromium than 420. but the carbon level is much lower than that of 420.
One significant difference lies in their corrosion resistance. 304 stainless steel is good resistant to corrosion, while 420 grade offers good corrosion resistance in mild environments, it is not as resistant as 304 stainless steel. In terms of strength and hardness, 420 steel excels. 304 stainless steel provides better ductility and toughness, but it is not as hard or strong as 420 alloy.